[Co(trien)(Cl)2]+
Triethylenetetramine (trien)
is a linear tetradentate ligand in which the nitrogen donor atoms are connected
by ethylene (two-carbon) linkges. In octahedral complexes, the trien
ligand occupies four coordination sites, leaving two open. Three different
geometric isomers are possible, differing in the way the ligand is wapped
around the metal center; the symmerical-cis (alpha-cis), unsymmetrical
cis (beta-cis) and trans. Furthermore, the symmetrical-cis
and unsymmeytrical-cis have nonsuperimposable mirror images
(not shown) giving a total of five stereoisomers.
|
Symmetrical-cis (alpha-cis) Isomer |
Unsymmetrical-cis (beta-cis) Isomer |
|
Trans Isomer |